Estimation Of Nickel Ii Using Dimethylglyoxime Dmg
- Dimethylglyoxime Nickel Test
- Estimation Of Nickel Ii Using Dimethylglyoxime Dmg File
- Estimation Of Nickel Ii Using Dimethylglyoxime Dmg Download
- Estimation Of Nickel(ii Using Dimethylglyoxime Dmg)
Table of Content
| Page | ||
| 1. | Title of experiment | |
| 2. | Table of contents | |
| 3 | Abstract | 2 |
| 4. | Introduction | 3 |
| 5. | Materials and methods | 4 |
| 6 | Results | 6 |
| 7 | Discussion | 8 |
| 8. | Conclusion | 10 |
| 9. | Reference | 11 |
Abstract
Dimethylglyoxime Nickel Test
Swi-prolog download for mac. The main objective of this experiment is to determine the concentration of nickel (II) ion in a nickel sample solution of unknown concentration. Gravimetric method is used whereby dimethylglyoxime (1% in alcohol) is added to precipitate the analyte which is later separated from the solution and dried. The concentration of the sample solution has been calculated as 0.109 mg/mL.
- Introduction
However, dimethylglyoxime (DMG) has rarely been used as a ligand in these ion-imprinting polymerisation reactions. DMG has been used for the determination of nickel using colourimetric. Nickel induces hyperglycemia and glycogenolysis and affects the antioxidant system in liver and white muscle of goldfish Carassius auratus L. Ecotoxicology and Environmental Safety 2012, 80, 231-237.
In this lab, you will be precipitating nickel (Ni2+) from an unknown Nickel ore. You will need to determine the % of nickel in the unknown which you will report on your unknown card and your lab report. Accuracy will play a large part of your grade so do every step CAREFULLY!
Nickel is precipitated with an organic precipitating agent termed dimethylglyoxime (DMG) as shown below. Organic reagents often react with more than one metal ion, therefore, adequate specification can be achieved with concentration and pH. DMG forms a chelating complex with the metal ion and forms a bright red precipitate Ni(C4H7N2O2)2 in a slightly basic solution of 1:1 aqueous ammonia. The precipitate is washed with a 30% ethanol solution and weighed (constant weight) after drying the frits in the oven at 110EC for 2 hours.
- Background Information of Method
The gravimetric method used in this experiment is among the most accurate methods but time-consuming. Overall, this method includes precipitation of the analyte in aqueous solution which is then separated from the mother liquor, washed, heated to constant weight and weighed as compound of definite composition.
Technique used
Gravimetric analysis is one of the most accurate analytical methods available. It is concerned with the determination of a substance by the process of weighing. The element or radical to be determined is converted into a stable compound of definite composition and the mass of the compound is determined accurately. From this, the mass of element or radical is calculated.
The gravimetric analysis involves
a) precipitation
Construction schedule software for mac. b) filtration
c) washing of the precipitate and
d) drying, ignition and weighing of the precipitate.
- Rationale / Purpose of Experiment
This experiment aims to determine the concentration of the nickel (II) ion (Ni2+) in a sample solution that contains it.
- Background Information of Analyte
The analyte in this experiment is Ni2+. As an element, it is one of the transition metals alongside copper, zinc, iron, manganese, etc. In ionic form, it usually possesses a charge of +2 and gives the solution containing it a green colour. When in contact with basic chemicals, such as aqueous sodium hydroxide (NaOH) and ammonia, it precipitates into a green nickel salt compound; this means nickel (II) solution is acidic. In this experiment, it comes in contact with dimethylglyoxime (DMG, C4H6(NOH)2) and precipitated as nickel dimethylglyoximate (Ni(DMG)2) in red.
Estimation Of Nickel Ii Using Dimethylglyoxime Dmg File
- Materials and Methods
- Apparatus
Volumetric flask (100 mL), beaker (400 mL), labelling tape, pipette (20 mL), measuring cylinder, microwave oven, thermometer, dropper, electronic weigh, glass rod, basin, sintered glass crucibles, desiccator, tongs, blue litmus paper, aspirator, side-arm filtering flask, retort stand, retort clamps.
- Chemicals and Reagents
Nickel (Ni2+) sample solution, distilled water, dimethylglyoxime (DMG, 1% in alcohol), nitric acid (HNO3, 6 M), urea, oxalic acid, dilute ammonium hydroxide (NH4OH).
- Experimental Procedures
A sample of nickel solution in a 100 mL volumetric flask is obtained and diluted to the mark with distilled water. The flask is shaken to mix the solution thoroughly and three aliquot samples (20 mL) are transferred into separate 400 mL beakers using a pipette. Each replicate is labelled as 1, 2 and 3 respectively and added distilled water (approximately 150 mL) before being heated to around 80°C in a microwave oven. DMG (10 mL) is added slowly to each replicate which their acidity are later checked with blue litmus paper. HNO3 (6 M) is added dropwise if any of the replicates is not acidic. Urea (3 g) is weighed and added to each replicate and stirred. The mixture is heated to boil for 3 minutes and cooled down to room temperature in a water-filled basin. Each replicate containing precipitate is added a few drops of dilute NH4OH. If the drop does not form red coloration upon mixing with the solution, precipitation is considered complete.
Estimation Of Nickel Ii Using Dimethylglyoxime Dmg Download
Three clean sintered glass crucibles, labelled 1, 2 and 3 respectively, are placed in a dessicator using tongs and weighed separately. The crucibles are then attached to the mouth of filtering flasks which are connected to the aspirator. The supernatant liquid (100 mL) of the mixture is decanted through the respective crucibles and the mixture in each replicate is stirred before being filtered through the crucibles using suction (vacuum filtration) for about 10 minutes. All the red precipitate is made sure to have been transferred into the crucible. The precipitate is washed with a few portions of distilled water (10 mL) before being dried in the oven until constant weight. When the experiment is completed, the crucibles are washed and rinsed in oxalic acid to remove unwashed precipitate.
- Results and Discussion
Overall, the experiment was conducted without any unfortunate incidents. A few errors occurred during the conduct of experiment, which will be explained further in the discussion section….CONTINUED
IMPORTANT!! Purchase to download the entire lab report below (11pages)